Characterization of the pyrolysis process of expanded polystyrene waste

Main Article Content

Arantxa Montserrat Gonzalez Aguilar
José Manuel Riesco Ávila
Francisco Elizalde Blancas
María Elena Tejeda del Cueto

Abstract

From the different existing methods for plastic recycling, pyrolysis offers the possibility of solving mechanical recycling limitations, which requires large amounts of clean, separate and homogeneous plastic waste in order to be able to guarantee the quality of the final product. In pyrolysis, it is not necessary to classify or clean the different types of plastic waste and it is possible to process waste contaminated with food and chemical products, such as insecticides, herbicides and fertilizers, reducing classification and cleaning costs. Pyrolysis consists of the chemical decomposition of plastic materials by thermal degradation in the absence of oxygen. In this work the results obtained from the pyrolysis of
waste expanded polystyrene (EPS) in a batch reactor, varying the pyrolysis temperature are presented. It was experimented with a mass of 500 g and temperatures of 350, 400 and 450 ° C. The results indicate that the highest conversion performance in to liquid hydrocarbon was obtained at a temperature of 450 ° C. The lowest yield of liquid hydrocarbon was obtained at the temperature 350 ° C.

Article Details

Section

Artículos-11-2

Author Biographies

Arantxa Montserrat Gonzalez Aguilar, , ,

Departamento de Ingeniería Mecánica, Universidad de Guanajuato, Salamanca, Gto. México.

 

 

José Manuel Riesco Ávila, , ,

Departamento de Ingeniería Mecánica, Universidad de Guanajuato, Salamanca, Gto. México.

María Elena Tejeda del Cueto, , ,

Facultad de Ingeniería Mecánica y Ciencias Navales, Universidad Veracruzana, Boca del Río, Veracruz. México. 

How to Cite

Characterization of the pyrolysis process of expanded polystyrene waste. (2021). Ingenio Magno, 11(2), 135-146. https://revistas.santototunja.edu.co/index.php/ingeniomagno/article/view/2185

References

K.-B. Park, Y.-S. Jeong, B. Guzelciftci and J.-S. Kim, “Two-stage pyrolysis of polystyrene: Pyrolysis oil as a source of fuels or benzene, toluene, ethylbenzene, and xylenes,” Applied Energy, 2020.

Y. Zhang, D. Duan, H. Lei, E. Villota and R. Ruan, “Jet fuel production from waste plastics via catalytic pyrolysis

with activated carbons,” Applied Energy, vol. 251, pp. 1-17, 2019.

N. Sophonrat, L. Sandström, I. N. Zaini and W. Yang, “Stepwise pyrolysis of mixed plastics and paper for

separation of oxygenated and hydrocarbon condensates,” Applied Energy, vol. 229, pp. 314-325, 2018.

S. M. FakhrHoseini and M. Dastanian, “Predicting Pyrolysis Products of PE, PP and PET Using NRTL Activity Coefficient Model,” Hindawi Journal of Chemistry, pp. 1-5, 2013.

S. D. A. Sharuddin, F. Abnisa, W. M. A. W. Daud and M. K. Aroua, “A review on pyrolysis of plastic wastes,” Energy

Conversion and Management, vol. 115, pp. 308-326, 2016.

A. Sobko, “Generalized Van der Waals-Berthelot equation of state,” Doklady Physics, vol. 53, no. 8, pp. 416-

, 2008.

J. A. Onwundili, N. Insura and P. Williams, “Composition of products from the pyrolysis of polyethylene

and polystyrene in a closed batch reactor: Effects of temperature and residence time,” Journal of Analytical

and Applied Pyrolysis, vol. 86, no. 2, pp. 293-303, 2009.

L. Quesada, M. Calero, M. Martín-Lara, A. Pérez and G. Blázquez, “Characterization of fuel produced by pyrolysis of plasticfilm obtained of municipal solid waste,” Energy, vol. 186, pp. 1-9, 2019.

S. M. Al-Salem, “Thermal pyrolysis of high density polyethylene (HDPE) in a novel fixed bed reactor system for

the production of high value gasoline range hydrocarbons (HC),” Process Safety and Enviromental Protection,

vol. 127, pp. 171-179, 2019.

J.-L. Shie, J.-P. Lin, C.-Y. Chang, D.-J. Lee and C.-H. Wu, “Pyrolysis of oil sludge with additives of sodium and potassium compounds,” Resources, Conservation and Recycling, vol. 39, no. 1, pp. 51-64, 2003.

J. Zhou, Y. Qiao, W. Wang, E. Leng, J. Huang, Y. Yu and M. Xu, “Formation of styrene monomer, dimer and trimer in

the primary volatiles produced from polystyrene pyrolysis in a wire-mesh reactor,” Fuel, vol. 182, pp. 333-339,

T. Faravelli, M. Pinciroli, F. Pisano, G. Bozzano, M. Dente and E. Ranzi, “Thermal degradation of polystyrene,”

Journal of Analytical and Applied Pyrolysis, vol. 60, no. 1, pp. 103-121, 2001.

I. C. McNeill, M. Zulfiqar and T. Kousar, “A detailed investigation of the products of the thermal degradation

of polystyrene,” Polymer Degradation and Stability, vol. 28, no. 2, pp. 131-151, 1990.

M. Artetxe, G. Lopez, M. Amutio, I. Barbarias, A. Arregi, R. Aguado, J. Bilbao and M. Olazar, “Styrene recovery from polystyrene by flash pyrolysis in a conical spouted bed reactor,” Waste Management, vol. 45, pp. 126-133, 2015.

S. I. Moqadam, M. Mirdrikvand, B. Roozbehani, A. Kharaghani and M. R. Shishehsaz, “Polystyrene pyrolysis using

silica-alumina catalyst in fluidized bed reactor,” Clean Techn Environ Policy, vol. 17, pp. 1847-1860, 2015.

A. Demirbas, “Pyrolysis of municipal plastic wastes for recovery of gasolinerange hydrocarbons,” Journal of

Analytical and Applied Pyrolysis, vol. 72, no. 1, pp. 97-102, 2004.

Y. Liu, J. Qian and J. Wang, “Pyrolysis of polystyrene waste in a fluidized-bed reactor to obtain styrene monomer

and gasoline fraction,” Fuel Processing Technology, vol. 63, no. 1, pp. 45-55, 2000.

A. Karaduman, E. Simsek, B. Cicek and A. Y. Bilgesü, “Flash pyrolysis of polystyrene wastes in a free-fall reactor under vacuum,” Journal of Analytical and Applied Pyrolysis, vol. 60, no. 2, pp. 179-186, 2001.

PlasticsEurope, “Reciclado y Recuperación de energía,” 2019. [Online]. Available: https://www.plasticseurope.org/es/focus-areas/circular-economy/zero-plasticslandfill/recycling-and-energyrecovery.

P. T. Williams and E. Slaney, “Analysis of products from the pyrolysis and liquefaction single plastics and

waste plastic mixtures,” Resources, Conservation and Recycling, vol. 51, no. 4, pp. 754-769, 2007.